Product ID:50-712 WHITE TREE
MSDS Date:06/04/1990
FSC:8010
NIIN:01-273-9348
MSDS Number: BHXHC

NILES CHEMICAL PAINT CO.

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 616-683-3377

Info Phone: 219-236-5856

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 37%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

PROPANE/ISOBUTANE (VAPOR PRESSURE 4400 MM @ 20 C)

CAS: 68476-86-8

Fraction By Weight: 18%

OSHA PEL 1000 PPM

ALKYD RESIN

Fraction By Weight: 15%

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 3%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: <1%

OSHA PEL 200 PPM/300 STEL

ACGIH TLV: 200 PPM/300STEL 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

COBALT (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

MANUFACTURER STATES UNIDENTIFIED INGREDIENTS ARE NOT

RTECS: 9999999ZZ

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SEVERE EYE IRRITATION, PERMANENT BRAIN
& NERVOUS SYSTEM DAMAGE FROM CHRONIC REPEATED & PROLONGED EXPOSURE,
DISORIENTATION, FROSTBITE, LIVER ABNORMALITIES, EYE DAMAGE. SKIN:
IRRITATION, DEFATTING OF SK IN, LEADING TO DERMATITIS. INHALED:
NASAL & RESPIRATORY IRRITATION, CNS DEPRESSION, UNCONSCIOUSNESS
EVEN ASPHYXIATION.
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC OR OSHA.
Effects of Overexposure:EYES: SLIGHT IRRITATION. SKIN: REDNESS &
IRRITATION, DEFATTING OF THE SKIN LEADING TO DERMATITIS. BREATHING:
NASAL & RESPIRATORY IRRITATION, CNS DEPRESSION, DIZZINESS, NAUSEA,
HEADACHE, VERTIGO, POSSI BLE UNCONSCIOUSNESS, EVEN ASPHYXIATION.
Medical Cond Aggravated by Exposure:NONE KNOWN

First Aid:INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN IF DIFFICULTY
BREATHING, CPR IF BREATHING HAS STOPPED. GET MED ATTN. SKIN:WASH
WITH SOAP & WATER. IMMED REMOVE CONTAMINATED CLOTHES. REUSE ONLY
WHEN CLEAN. IF PERSISTENT IRRITATION OCCURS, GET MED ATTN.
EYES:IMMED FLUSH W/LARGE AMOUNTS OF WATER AT LEAST 15 MINS, LIFTING
LIDS. GET MED ATTN. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING
W/THIS MATERIAL.

Flash Point:NR
Autoignition Temp:Autoignition Temp Text:806 F
Lower Limits:0.8
Upper Limits:20.0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE & FULL PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:CANS WILL RUPTURE FROM INTERNAL PRESSURE
AT ABOUT 190F & DISCHARGE FLAMMABLE CONTENTS. WHEN HEATED TO
DECOMP, TOXIC FUMES ARE FORMED. VAPORS ARE HEAVIER THAN **

Spill Release Procedures:ELIMINATE ALL IGNITE SOURCES(FLAME, HOT
SURFACES, ELECTRICAL, STATIC, FRICTIONAL SPARK). MINIMIZE BREATHING
VAPORS & AVOID SKIN CONTACT. ABSORB W/INERT MATERIAL: CLAY, SOIL,
COMMERCIAL ABSORBENT. SHOV EL RECLAIMED LIQ/ABSORB INTO
RECOVERY/SALVAGE DRUM

Handling and Storage Precautions:DO NOT STORE ABOVE 120 F. STORE LARGE
QUANTITIES IN AREAS DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS
1A FLAMMABLE LIQUIDS.
Other Precautions:DON'T SPRAY IN EYES. DON'T PUNCTURE/INCINERATE CAN.
DON'T STICK PIN/ANY SHARP OBJECT INTO OPENING ON TOP OF CAN. FINGER
MUST NOT PROTRUDE OVER FRONT OF SPRAY BUTTON. MISUSE BY
DELIBERATELY CONCENTRATI NG & INHALING MAY BE HARMFUL EVEN FATAL

Respiratory Protection:FOR CASUAL USE, NONE REQUIRED, PROVIDED
VENTILATION IS PROVIDED AS OUTLINED IF EYEWATERING, HEADACHES OR
DIZZINESS OCCUR, INCREASE VENTILATION OR WEAR RESPIRATOR PROTECTION
(NIOSH/MSHA TC 23C OR EQUIV ALENT) OR LEAVE AREA.
Ventilation:SUFFICIENT VENTILATION IN VOLUME/PATTERN TO KEEP AIR
CONCENTRATE BELOW CURRENT APPLICABLE OSHA PEL/TLV STANDARD LIMITS.
Protective Gloves:NONE REQUIRED.
Eye Protection:NONE REQUIRED.
Other Protective Equipment:NONE REQUIRED.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, SMOKING
OR USING RESTROOM.
Supplemental Safety and Health

Boiling Pt:B.P. Text:<0F,<-18C
Decomp Temp:Decomp Text:N/E
Vapor Density:> THAN AIR
Viscosity:****
Evaporation Rate & Reference:< THAN ETHER (SOLVENT) *
Appearance and Odor:VAPOR, ODOR OF SOLVENTS. * EVAPORATION RATE: > THAN
ETHER (PROPELLENT).
Percent Volatiles by Volume:76.30

Stability Indicator/Materials to Avoid:YES
N/K. ** AIR, MAY TRAVEL ALONG GROUND TO IGNITION SOURCES. ISOLATE FROM
HEAT, SPARKS, ELECTRICAL EQUIPMENT & OPEN FLAMES.
Stability Condition to Avoid:N/K. (THIS MATERIAL HAS BEEN FOUND TO BE
STABLE UNDER REASONABLE CONDITIONS OF STORAGE & USE).
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CARBON MONOXIDE AND
PHOSGENE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.